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Diffusional Behavior of Poly(diethylsiloxane) in the Liquid Crystalline and Isotropic Phases As Studied by High Field-Gradient NMR

✍ Scribed by Kanesaka, Sho; Kimura, Hideaki; Kuroki, Shigeki; Ando, Isao; Fujishige, Shouei


Book ID
111886602
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
107 KB
Volume
37
Category
Article
ISSN
0024-9297

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## Abstract The structure of poly(diethylsiloxane) (PDES) has been characterized using solid‐state NMR of ^17^O. The sample studied had a weight‐average molecular weight of 2.45 Γ— 10^5^. The sample was prepared by utilizing the cationic ring‐opening polymerization of ^17^O‐enriched hexacyclotrisilo