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Diffusion of transition metals in “in situ” duplex oxide grown on a 316 stainless steel

✍ Scribed by A. F. Smith; R. Hales


Publisher
John Wiley and Sons
Year
1978
Tongue
German
Weight
383 KB
Volume
29
Category
Article
ISSN
0947-5117

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✦ Synopsis


Abstract

Concentration profiles of chromium, maganese and iron radioactive tracers through a duplex oxide grown on 316 stainless steel have been obtained after a diffusion anneal at 1273 K using the serial sectioning technique. The iron tracer diffused normally in both inner and outer oxides of the duplex scale. The concentration of the chromium and manganese tracers increased with increasing penetration into the outer Fe~3~O~4~ layer but showed a normal profile in the inner spinel. The diffusion coefficients obtained from the profiles were in the range 6 × 10^−12^ – 3 × 10^−11^ cm^2^ sec^−1^ for diffusion in the spinel phases.