Diffusion of Dioxygen in Alkanes and Cycloalkanes
β Scribed by Kowert, Bruce A.; Dang, Nhan C.; Reed, Joshua P.; Sobush, Kurtis T.; Seele, Louis G.
- Book ID
- 126973786
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 72 KB
- Volume
- 104
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
Normal and cyclic alkanes and alkenes form stable gas-phase ions in air at atmospheric pressure from 40 to 200Β°C when moisture is below 1 ppm. Ionization of alkanes in a (63)Ni source favored charge transfer over proton transfer through pathways involving [M-1](+) and [M-3](+) ions. Ion mobility spe
Direct iodination of alkanes and cycloalkanes in the presence of superelectrophiles has been accomplished for the first time. The reactions of saturated hydrocarbons with I 2 in the presence of CCl 4 β’2AlI 3 at -20Β°C afforded monoiodides in good yields and selectivities.