Analyses of the excited-state proton transfer reaction of 1-naphthol in sapphire/water interface layers have been performed using fluorescence decay data obtained by a picosecond time-resolved total internal reflection fluorescence spectroscopy. The rate constant of the excited-state proton transfer
Diffusion effect on excitation energy transfer in solution: Analysis by means of picosecond time-resolved fluorimeter
โ Scribed by Naoto Tamai; Tomoko Yamazaki; Iwao Yamazaki; Noboru Mataga
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 366 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Excimtion energy wansfer between rhodnmine 6G (energy donor) a.nd maInchile green (acceptor) has bcrn srudisd by means of n picosecond time-resolved. single-pholon counting wchnique. Donor fluorrsc~~~r dccnys were satisfaclorily analyzed in terms of the theorcknl decay function including translalional diffusion proposed by G6sele et al. A simple Fiirshzr cqualion withoul considering the diffusion is found LO orvresIima[e the criknl lmnsfer distance.
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Femtosecond-picosecond time-resolved absorption spectral measurements on 9,9'-bianthryl in polar alkanenitrile solvents revealed that the rise curve of the charge-transfer (CT) state contained components with rise times considerably longer than the solvent 7L, which indicated the importance of the t