Diffusion-controlled reactions in presence of polymers
โ Scribed by C. von Ferber; Yu. Holovatch
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 166 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0167-7322
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โฆ Synopsis
We study the properties of diffusion controlled reactions with traps or reaction sites attached to polymer chains or to a star polymer. Using a field theoretical renormalization group approach we obtain the scaling of the moments of concentration of diffusing particles near the core of a star polymer and calculate numerical values of the exponents governing the scaling of the reaction rate.
๐ SIMILAR VOLUMES
The Taylor dispersion technique has been used to measure the diffusion coefficients of nine compounds in dilute solution in isopropanol at 300 K. These compounds correspond, by the difference of a single hydrogen atom, to nine free radicals, for which the rate constants for bimolecular (termination)