Photografting reaction onto styrene-butadiene rubber (SBR) as a function of monomer concentration, grafting method, irradiation time, and the carbon black content has been studied using ultraviolet (UV). Glycidyl methacrylate and benzophenone are used as monomer and initiator, respectively. The occu
Diffusion and sorption behavior of glycidyl methacrylate in styrene butadiene rubber
โ Scribed by Kum Kang Hwang; Sung Hun Ryu; Seong Uk Hong
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 143 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0021-8995
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โฆ Synopsis
Abstract
In this study, the diffusion and sorption behavior of glycidyl methacrylate in styrene butadiene rubber (SBR) was investigated as a function of waste tire powder content, sulfur content (i.e., the crosslink density), and temperature by using the gravimetric sorption method. The results indicate that penetrant solubility increases as sulfur and waste tire powder contents decrease, whereas the temperature affects the solubility favorably. The results also indicate that mutual diffusion coefficients decrease as the sulfur and waste tire powder contents increase. This behavior was interpreted in terms of free volume of the polymer and tortuosity. ยฉ 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2701โ2706, 2002
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