Diffusion and convection after escape from a potential well
โ Scribed by B.U. Felderhof
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 778 KB
- Volume
- 388
- Category
- Article
- ISSN
- 0378-4371
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โฆ Synopsis
The escape by diffusion of a particle from a potential well in one dimension is strongly influenced by the application of a field in the adjacent half-space. At long times the probability distribution becomes a uniformly moving and steadily broadening gaussian in this half-space. The mean time of escape from the well is given by a simple expression in terms of the mean first passage time and the coefficient of the long-time tail in the occupation probability of the well in the absence of the field. Transient effects in space and time are studied in explicit form for a parabolic potential well.
๐ SIMILAR VOLUMES
The Kramers theory of chemical kinetics is modified in order to describe the escape of particles from a potential well of the Lennard-Jones type, for which there is no well-defined barrier position or curvature. Approximate analytical methods are used to derive from the Fokker-Planck equation two d
The problem of escape of a particle by diffusion from a square potential well across a square barrier is studied on the basis of the one-dimensional Smoluchowski equation for the space-and time-dependent probability distribution. For the model potential the Smoluchowski equation is solved exactly by