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Diffuse Double-Layer Interaction between Two Identical Spherical Colloidal Particles

✍ Scribed by Hiroyuki Ohshima

Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 69 KB
Volume: 225
Category: Article
ISSN: 0021-9797
DOI: 10.1006/jcis.2000.6746

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✦ Synopsis

A simple method is given for calculating the potential energy of the diffuse double-layer interaction between two identical spherical colloidal particles in a symmetrical electrolyte solution with the help of Derjaguin's approximation. This method uses accurate analytic expressions for the corresponding interaction energy between two parallel similar plates obtained previously (Colloids Surf. A Physicochem. Eng. Asp. 146, 213 (1999); J. Colloid Interface Sci. 212, 130 (1999)). Agreement with numerical data provided by Honig and Mul (J. Colloid Interface Sci. 36, 258 (1971)) is excellent particularly for small particle separations. Copyright 2000 Academic Press.

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