Differentiation of excited-state and biradical processes. Photochemistry of phenyl alkyl ketones in the presence of oxygen
โ Scribed by Small, R. D.; Scaiano, J. C.
- Book ID
- 127050199
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 979 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Alkyl aryl ketones undergo Type II photoreaction both on a silica-gel surface and in solution. The amount of acetophenone produced from valerophenone increases linearly with increase in the amount of valerophenone loaded at coverage below ca 60%. The effect of the alkyl chain length on the Type II p
## Abstract For Abstract see ChemInform Abstract in Full Text.
The photochemical behavior of the 2-pyridyl phenyl ketone was studied by stationary techniques in sodium dodecyl sulfate submicellar and micellar solutions. Nanosecond laser flash photolysis was employed to identify the primarily produced transients. The photochemistry is mainly due to fast intramol