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Differentiation between isomeric 2-thionosparteine and 15-thionosparteine on the basis of electron ionization mass spectra

✍ Scribed by Renata Kolanoś; Waleria Wysocka


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
71 KB
Volume
38
Category
Article
ISSN
1076-5174

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✦ Synopsis


Differentiation between isomeric 2-thionosparteine and 15-thionosparteine on the basis of electron ionization mass spectra


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Stereochemical effects on the electron-impact (El)-induced fragmentation of cis/trans-and diendo/diexo-fused stereoisomers of several 2,3dihydrothiazolo[3,2+]pyrimidin-5-ones and 3,4-dihydropyrimido[2,1-b]thiazinh n e s annelated to various saturated and unsaturated carbocycles were studied. The ret