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Differential Pulse Voltammetric Determination of Free Chlorine for Water Disinfection Process

✍ Scribed by Sulistyo Saputro; Kô Takehara; Kazuhisa Yoshimura; Shiro Matsuoka; Narsito


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
188 KB
Volume
22
Category
Article
ISSN
1040-0397

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✦ Synopsis


Abstract

The electrochemical detection of free chlorine based on the reduction at a gold electrode has been studied. The differential pulse voltammetric curves exhibited well‐defined cathodic peaks. Investigations with this system suggested that the active species in the cathodic reaction is HClO. Excellent reproducibility was demonstrated at pH 5. The peak height could be used for accurate and rapid determination of free chlorine in a sample water. A linear relationship (r^2^=0.99) was found for the concentration range of 1–5 mg Cl dm^−3^ and the detection limit was estimated to be 0.04 mg Cl dm^−3^.


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