A new method of speciation by differential pulse polarography (DPP) is described. It is focused on non-labile complexes on the DPP time scale. By solving mass-balance equations -which are written for the labile part of a metal-ligand system -free metal, free ligand and non-labile complex concentrati
β¦ LIBER β¦
Differential pulse polarographic studies of copper(II)-polyamine complexes at low ligand concentrations
β Scribed by Norman E. Schmidt; Jing Hao Pan; Robert H. Philp Jr.
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 532 KB
- Volume
- 241
- Category
- Article
- ISSN
- 0022-0728
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The influence of 2-hydroxy-3-[(2-hydroxy-1,1-dimethylethyl)amino]propane-1-sulfonic acid (AMPSO HL) on systems containing copper(II) was studied by glass-electrode potentiometry (GEP) and direct-current polarography (DCP), at fixed total-ligand-to-total-metal-concentration ratios and various pH valu