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Differential non-destructive image current detection in a fourier transform quadrupole ion trap

✍ Scribed by Badman, Ethan R.; Patterson, Garth E.; Wells, J. Mitchell; Santini, Robert E.; Cooks, R. Graham


Book ID
101223469
Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
84 KB
Volume
34
Category
Article
ISSN
1076-5174

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✦ Synopsis


Dual-detector differential non-destructive Fourier transform detection in a quadrupole ion trap is shown to improve signal intensity and reduce noise compared with spectra recorded using a single detector. A larger area detector in each end-cap electrode is machined to fit its hyperbolic shape and so minimize field imperfections on the z-axis. Argon, acetophenone and bromobenzene spectra were recorded to allow a comparison between single- and dual-detector (differential) modes of detection and to demonstrate the improvement achieved with differential detection. Copyright 1999 John Wiley & Sons, Ltd.


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## Abstract A Fourier transform operating mode is applied to an ion trap. The trap is truncated at 2__r__~0~ and presents unwanted defects that induce confinement electric‐field non‐linearities. Ion axial secular‐motion spectrum is examined by experiments near the resonance line β~__z__~ = 0.5. Io