Differential-kinetic model of the polyesterification of terephthalic acid with ethylene glycol without catalyst
β Scribed by M. P. Vladimirova; V. V. Kiselev; V. A. Malykh; A. S. Chegolya
- Publisher
- Springer US
- Year
- 1977
- Tongue
- English
- Weight
- 370 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0015-0541
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π SIMILAR VOLUMES
The polyesterification between adipic acid and ethylene glycol in nonequimolar ratios was investigated. The kinetic equations obtained were quite different from those obtained by Flory in equimolar systems. The kinetic equations obtained in this study were -d[COOH]/dt = k [COOH] [OHI2 for uncatalyze
This research focused on the kinetics of diethylene glycol (DEG) formation from the bishydroxyethyl terephthalate (BHET) monomer with a proton catalyst. In this study, the effect of proton concentration and of reaction temperature on DEG formation are discussed. Also, the rate equation of DEG format