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Different Reactivity of Hydroxylamine with Carbamoyl Azides and Carbamoyl Cyanides: Synthesis of Hydroxyureas and Carbamoyl Amidoximes

✍ Scribed by Paz, Jairo; Pérez-Balado, Carlos; Iglesias, Beatriz; Muñoz, Luis

Book ID
111890748
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
938 KB
Volume
75
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES

Thermolysis of Carbamoyl Azides. II. A.
Thermolysis of Carbamoyl Azides. II. A. Novel Reduction of Azides with Elemental Copper
✍ Werner Reichen 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 German ⚖ 507 KB

## Abstract Copper(0) does not catalyze the decomposition of dialkylcarbamoyl azides **5a–e** but instead it is oxidized to copper(II) while the azides **5** are reduced by uptaking one electron per molecule and eliminating nitrogen. A probable explanation for the formation of the resulting copper(