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Different coordination environments in pseudooctahedral complexes of Cr(III) and Co(III) with dithiocarbazic acids

✍ Scribed by C. Battistoni; G. Mattogno; A. Monaci; F. Tarli


Publisher
Elsevier Science
Year
1971
Weight
168 KB
Volume
7
Category
Article
ISSN
0020-1650

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Stereoselectivity in reactions of metal
✍ Gérard Colomb; Klaus Bernauer 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 German ⚖ 370 KB

## Abstract The synthesis of mixed‐ligand cobalt(III) complexes with (__S__)‐aspartic‐N‐monoacetic acid ((__S__)‐AMA) and different amino‐acids Na[Co((__S__)‐AMA)(AA)] (AA = gly, (__R__)‐ and (__S__)‐ala, val, phe, ser and leu) leads to a mixture of __cis__‐N‐ and __trans__‐N‐isomers. These isomers