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Differences in the keto–enol equilibrium of [M + H]+ ions of bupropion formed by electron impact and fast atom bombardment ionization

✍ Scribed by Robert L. Johnson; Lester C. E. Taylor

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
385 KB
Volume
28
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The fragmentation of the protonated molecular ion of bupropion produced by collisionally induced decomposition is shown to depend on the ionization method used to form the [M + H]^+^ ion. The daughter ion products do not depend on the energy of decomposition, i.e. high‐ or low‐energy collisions, but on the ratio of the keto‐enol equilibrium as influenced by the ionization process.

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