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Diethyl 3-methyl-5-(triphenylphosphoranyleneamino)thiophene-2,4-dicarboxylate

✍ Scribed by Jiao, Yuan-Hong ;Zhang, Qian ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
460 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title iminophosphorane, C~29~H~28~NO~4~PS, a thiophene compound with the sterically crowded –N=P(C~6~H~5~)~3~ substituent in the α-position of the aromatic ring, features an N =P double bond of length 1.572 (3) Å. One of the phenyl rings is coplanar with the plane of the three ipso-C atoms, whereas the other two are approximately orthogonal.


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