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Dienophilic reactivity of perfluoroalkenyl ketones in Diels–Alder reactions

✍ Scribed by Frédéric Chanteau; Michael Essers; Richard Plantier-Royon; Günter Haufe; Charles Portella

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 115 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)00107-7

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✦ Synopsis

Perfluoroalkenyl ketones, obtained by reaction of perfluoroorganometallic reagents with acylsilanes, are shown to be versatile dienophiles in Diels-Alder reactions with various dienes.

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