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Dienophilic and dipolar additions to bicyclo[2.1.0]pent-2-ene

✍ Scribed by Waldemar Adam; Axel Beinhauer; Ottorino De Lucchi; Robert J. Rosenthal

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
230 KB
Volume
24
Category
Article
ISSN
0040-4039

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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond