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Dienone intermediates in the Pummerer rearrangement of 4-methylsulfinyl-3,5-xylenol

โœ Scribed by King, Russell R.


Book ID
127215884
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
302 KB
Volume
43
Category
Article
ISSN
0022-3263

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A 5, 7-membered fused-ring compound with a fianctionalized angular substituent, 8-methoxy-8act-methoxymethyl-7-phenylthio-1, 2, 3, 6-tetrahydro-3acq 613-epoxyazulene, was synthesized via a tandem Pummerer rearrangement and intramolecular [4+3] cycloaddition.