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Dienes as chiral templates

โœ Scribed by Dietmar Schomburg; Marion Thielmann; Ekkehard Winterfeldt


Book ID
104219417
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
120 KB
Volume
27
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Stereoselectlve and regloselectlve cycloaddltlons to the choral cyclopentadlene z are reported. Dlastereoselectlve transformations of the adducts followed by a thermal retroreactlon yields pure enantlomers. CambrIdge CH2 LEW, U.K. Thanks are due t II Dr. r. tiofer b: for a sprlrs of shift-mear;urelnents.


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A facile synthetic method of chiral glycine and a new access to chiral acetic acid based on a concept of chirality transfer from glucose are described. Recently, we demonstrated usefulness of a technique consisting of the stereospecific chiral labeling of a prochiral methylene group by deuterium and