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Dienediolates from unsaturated carboxylic acids: Michael addition of dilithium buta-1,3-diene-1,1-diolate (from crotonic acid) to unsaturated ketones

✍ Scribed by Ballester, Pablo; Costa, Antonio; Raso, Angel Garcia; G�mez-Solivellas, Antonio; Mestres, Ramon


Book ID
121717461
Publisher
Royal Society of Chemistry
Year
1988
Weight
878 KB
Volume
7
Category
Article
ISSN
1472-7781

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and treated with lBuCl (1.18 g, 12.8 mmol) directly after filtration. The mixture was stirred at room temperature for 12 h before the orange solution was evaporated to dryness. Recrystallization of the residue from toluene (ca. 30 mL) affords a yellow crystalline powder (2.50 g, 40%). which decompos