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Diels?Alder reactions of polyfluorocyclohexa-1,3-dienes. Part IV. Addition of alkynes to 1H,2H-hexafluorocyclohexa-1,3-diene

✍ Scribed by Feast, W. J.; Musgrave, W. K. R.; Weston, R. G.

Book ID
120601649
Publisher
The Royal Society of Chemistry
Year
1971
Tongue
English
Weight
393 KB
Volume
0
Category
Article
ISSN
0022-4952

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An improved cobalt catalyst for homo Die
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✍ Gerhard Hilt; François-Xavier du Mesnil 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 121 KB

An ecient cobalt(I)-catalysed homo Diels±Alder reaction of acyclic 1,3-dienes and acetylene derivatives is described. The catalyst system consists of a mixture of a readily available CoBr 2 (dppe) complex, zinc iodide as a cocatalyst, and tetrabutylammonium borohydride as reducing agent. This system