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Diels–Alder reactions of N-tosylpirroles developed in protic ionic liquids. Theoretical studies using DFT methods

✍ Scribed by Claudia Della Rosa; Carla Ormachea; Maria N. Kneeteman; Claudia Adam; Pedro M.E. Mancini


Book ID
113930118
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
241 KB
Volume
52
Category
Article
ISSN
0040-4039

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Diels–Alder reactions of nitrobenzofuran
✍ Claudia D. Della Rosa; Juan P. Sanchez; María N. Kneeteman; Pedro M.E. Mancini 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 259 KB

a b s t r a c t 2-and 3-nitrobenzofurans are studied in polar thermal Diels-Alder reactions with normal electron demand using several structurally different dienes. A very strong electron-acceptor group, such as the nitro group, pushes the dienophilic character of these heterocyclic compounds. Since