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Diels—Alder Reactions of 4-Alkoxy-4-alkylcyclohexa-2,5-dienimines: Synthesis of 5-Alkylindoles.

✍ Scribed by Peter V. Zawada; Scott C. Banfield; Michael A. Kerr

Publisher
John Wiley and Sons
Year
2003
Weight
194 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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✍ Rafael Martínez; Hugo A. Jiménez-Vázquez; Alicia Reyes; Joaquín Tamariz 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 339 KB 👁 2 views

The N-substituted isomeric (4Z,5Z)-and (4E,5Z)-4,5-diethylideneoxazolidin-2-ones 5 and 6 were synthesized, the latter being favored during the one-step process from the a-diketone 1c and different isocyanates. The steric interaction between the N-substituent and the Me group attached to the exocycli