Diels—Alder reactions catalysed by lanthanide chlorides
✍ Scribed by Shijian Liao; Shuwen Yu; Zhiyu Chen; Daorong Yu; Lei Shi; Renwu Yang; Qi Shen
- Book ID
- 103693771
- Publisher
- Elsevier Science
- Year
- 1992
- Weight
- 548 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0304-5102
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📜 SIMILAR VOLUMES
Diels-Alder reaction between cyclopentadiene and various dienophiles (mainly methacrolein) at -78°C was catalysed by various chiral aluminum alcoholates. The catalysts were prepared by reaction of EtAICl2 with several families of dial (or their monoether monoalcohol derivatives) . The most enantiose
In presence of bismuth (III) chloride, a carbonylated electrophile (ethyl mes oxalate or glyoxylate) and usual diene led selectively (65 to 100%) the hetero carbonyl-Diels-Alder reaction with the ene reaction product. BiCl 3 exhibits strong catalytic activity and, compared with previous literature,