Diels–Alder Reaction of Thiophene: Dramatic Effects of High-Pressure/Solvent-Free Conditions
✍ Scribed by Koji Kumamoto; Isao Fukada; Hiyoshizo Kotsuki
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 95 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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The kinetic pressure effect on some Michael-like and [4 2] cycloadditions in aqueous solution was studied. This effect is complex and variable, in contrast to the pressure dependence of rate constants in organic solvents. In order to determine the origin of this kinetic behavior, systematic solvent