## Abstract o‐Benzoquinone monoketals, generated in situ by oxidation of o‐methoxyphenols (I) in the presence of methanol, undergo Diels—Alder reaction with olefins (III) and dihydrofuran to give the endo adducts (IV) and (VI) selectively.
✦ LIBER ✦
Diels–Alder reaction of 4-halogenated masked o-benzoquinones with electron-rich dienophiles
✍ Scribed by Seshi Reddy Surasani; Rama Krishna Peddinti
- Book ID
- 113929687
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- French
- Weight
- 426 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4039
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The Diels-Alder reaction of 4-aryl-pyrones with electron-rich dienophiles afforded substituted biaryl derivatives in most cases. At the minimal temperatures necessary for a measurable conversion of the starting pyrones, the bicyclic lactones, the primary products of the condensation, underwent cyclo