Diels—Alder Reaction. Effect of Internal and External Factors on the Reactivity of Diene—Dienophile Systems
✍ Scribed by A. I. Konovalov; V. D. Kiselev
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 52 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## AM1 and PM3 computations show that thiocarbonyl S-oxide and thiocarbonyl S,S-Dioxide undergo Diels᎐Alder cycloadditions with cyclopentadiene and Ž . anthracene to form thiabicyclic adducts through asynchronous transition structures TSs with CϭS \* involving in the reaction at a very early stage
Diels-Alder reactions / 1,2-Dicyano-1,3-~yclobutadiene / Dewar benzenes / High-pressure reactions The trimerization of cyanoacetylene (la) and the Diels-Alder reaction of l a with 1,3-cyclohexadiene (2) show a powerful pressure-induced acceleration which allows the reaction temperature to be reduce