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Diels-Alder-Reaktionen. VIII. Kinetische Untersuchungen zur Bildung und zur Pyrolyse von Tetracyclo[6.2.1.13.6.02.7]dodec-4-en

✍ Scribed by Dr. K. K. Moll; Dr. K. Ramhold; Dr. Habil. G. Zimmermann; Ch. Pohle


Book ID
105352241
Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
301 KB
Volume
322
Category
Article
ISSN
1615-4150

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✦ Synopsis


Diels‐Alder‐Reactions. VIII. Kinetic Investigations of the Formation and the Pyrolysis of Tetracyclo [6.2.1.1^3.6^.0^2.7^]‐dodec‐4‐en

The formation of tetracyclo[6.2.1.1^3.6^.0^2.7^]dodec‐4‐ene by codimerisation of cyclopentadiene with bicyclo[2.2.1]hept‐2‐ene between 60 and 140°C in the liquid phase and the inverse reaction by gas phase pyrolysis between 240 and 300°C were studied kinetically. The activation parameters were determined.