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Diels-Alder reactivity of pyrano[3,4-b]indol-3-ones. Part 3. Intramolecular Diels-Alder reactions

✍ Scribed by Moody, Christopher J.; Shah, Pritom; Knowles, Philip

Book ID
120272938
Publisher
Royal Society of Chemistry
Year
1988
Weight
875 KB
Volume
12
Category
Article
ISSN
1472-7781

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Diels-alder reactions of pyrano[3,4-b]in
Diels-alder reactions of pyrano[3,4-b]indol-3-ones with olefinic compounds : Synthesis of (1,2-dihydro)carbazoles
✍ P. Van Doren; D. Vanderzande; S. Toppet; G. Hoornaert πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 701 KB

The role of the substitution pattern on the stability of the obtained 1.2-dihydreearbazolee is interpreted In terms of electronic and steric effects on the aromatization to the corresponding carbazoles. CH and 2-CHb bonds, a small coupling constant of 1,6 Hz is observed. A dihedral angle of about 26