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Diels-alder reactivity of 1-alkoxyphenyl-3-trialkylsiloxy-1,3-dienes

✍ Scribed by Marta Adeva; Esther Caballero; Francine García; Manuel Medarde; Heidi Sahagún; Fernando Tomé


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
244 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


The synthesis of 1-(3,4,5-trimethoxyphenyl)-3-trialkylsiloxy-l,3butadienes and their Diels-Alder reaction with selected dienophiles at room temperature is described. These aryldienes are useful building blocks for the synthesis of natural and pharmacological active products, as has been shown by the preparation of a tetracyclic ketone needed for the synthesis of new anthracycline analogues.


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ChemInform Abstract: Synthesis and Diels
✍ E. CABALLERO; F. GUILHOT; J. L. LOPEZ; M. MEDARDE; H. SAHAGUN; F. TOME 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

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