Diels-alder reactivity of 1-alkoxyphenyl-3-trialkylsiloxy-1,3-dienes
✍ Scribed by Marta Adeva; Esther Caballero; Francine García; Manuel Medarde; Heidi Sahagún; Fernando Tomé
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 244 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The synthesis of 1-(3,4,5-trimethoxyphenyl)-3-trialkylsiloxy-l,3butadienes and their Diels-Alder reaction with selected dienophiles at room temperature is described. These aryldienes are useful building blocks for the synthesis of natural and pharmacological active products, as has been shown by the preparation of a tetracyclic ketone needed for the synthesis of new anthracycline analogues.
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