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Diels-Alder Reactions of 4,5-Dimethylenedioxolanes

✍ Scribed by MILLER, J. B.


Book ID
121187221
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
898 KB
Volume
25
Category
Article
ISSN
0022-3263

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The frontier molecular orbital of 5-phenylcyclopentadiene was predicted on the basis of the orbital mixing rule to deform to favor the Diels-Alder reaction in a syn contrasteric manner. The prediction was substantiated experimentally by the reactions of 5-methyl-5phenylcyclopentadiene with dienophil