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Diels-Alder reactions of 2-pyrones. Direction of the addition reaction with acetylenes

✍ Scribed by Reed, Joe A.; Schilling, Curtis L.; Tarvin, R. F.; Rettig, Thomas A.; Stille, John K.


Book ID
126329415
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
642 KB
Volume
34
Category
Article
ISSN
0022-3263

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Regioselectivity in the diels-alder reac
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Ab5tract: 4-Ethyl-5-methyl-6-mthylthio-2(H)-pyranone (4) undergoes Dials-Alder reactions with ethyl hexynoate (5). 3-heptyn-2-one (6). ethyl ptopiolate (7). and3-butyn-2-one (8) to afford substituted banzenes with high ragioselectivity upon extrusion of CO2. 4-Ethyl-5.6-dimethyl-( 4-ethyl-3,6-dimeth