Several polymers containing AI Lewis acids anchored to chiral prolinol moieties have been prepared and studied as catalysts for the Diels-Alder reaction of cyclopentadiene and methacrolein. The chiral ti'agment has been introduced by grafting and by polymerisation procedures using different crosslin
✦ LIBER ✦
Diels-Alder Reactions in Polymer Chemistry: Synthesis of Pyridoxine on a Polymeric Backbone
✍ Scribed by Ritter, Helmut; Sperber, Rolf
- Book ID
- 121423629
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 164 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
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Hexafluoroisopropanol and trifluoroethanol are found to promote imino-Diels-Alder reactions of the N-aryl aldimine 1 with alkyl vinyl ethers to afford the corresponding tetrahydroquinolines in good yields without Lewis acid under mild and neutral conditions. The reaction is also efficient in a three