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Diels-Alder reaction of α-substituted 5-vinylisoxazoles

✍ Scribed by S. D. Sokolov; O. G. Azarevich; S. M. Vinogradova

Publisher
Springer US
Year
1988
Tongue
English
Weight
69 KB
Volume
24
Category
Article
ISSN
0009-3122

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The frontier molecular orbital of 5-phenylcyclopentadiene was predicted on the basis of the orbital mixing rule to deform to favor the Diels-Alder reaction in a syn contrasteric manner. The prediction was substantiated experimentally by the reactions of 5-methyl-5phenylcyclopentadiene with dienophil