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Diels-Alder reaction of in-situ generated 2-methoxycarbonyl-p-quinone with D-glucose based dienes: A new approach to forskolin

✍ Scribed by Aloka Mukhopadhyay; S.M. Ali; Mashkoor Husain; S.N. Suryawanshi; D.S. Bhakuni

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 270 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99597-2

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✦ Synopsis

Absbxxct: Diels-Alder reaction of 2-methoxycarbonyl-gquinone 2 with Ll_-glucose based dienes 4 (a-h) -7furnished cis-adducts 10 (a-h) in

a stereo-and regiospecific manner. Chemical transformation of 10 affoxd K-E. cornj&ds G 13 and G are key intermediates in the proposed synthesis of forskolin.

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