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Diels-alder reaction of 1-methylcycloprop-2-ene-1-carbonitrile with methyl 2-oxo-2H-pyran-5-carboxylate

✍ Scribed by V. V. Plemenkov; R. V. Ashirov; O. A. Lodochnikova; I. A. Litvinov; R. N. Zagidullin


Book ID
111464025
Publisher
SP MAIK Nauka/Interperiodica
Year
2006
Tongue
English
Weight
192 KB
Volume
42
Category
Article
ISSN
1070-4280

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Diels-Alder reaction of furan with methy
✍ Jacques Leroy πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 301 KB

Abs&cC The two epimers of methyl 3-oxo-7-oxabicyclo[2.2.l]hept-S-en-2-carboxylate have been prepared from furan and methyl 3-bromopropiolate as a melhoxycarbonylketcne equivalent. The final step required hydrolysis of acetals by Nafion-H. 7-Oxabicyclo[2.2.l]hept-5-en-2-yl derivatives, in an opticall