✍ Scribed by Harry E. Ensley; Shivkumar Mahadevan
No coin nor oath required. For personal study only.
Nitrosyl hydride and nitrosoformaldehyde have been prepared by the thermolysis of their 9,10-dimethylanthracene adducts. Both HMO and HCONO are found to be reactive as enophiles and dienophiles. Nitrosyl hydride or nitroxyl (HMO) has been the subject of numerous theoretical studies' and has been extensively studied in the gas phase. 2 HMO has been proposed as an intermediate in the combustion of nitrogeneous substances' and has been detected as a constituent of interstellar clouds." However, we are aware of no reports,of the solution reactions of HMO other than dimerization followed by decomposition to water and N,0.2b Kirby has reported the
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