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Dielectric spectroscopy and molecular dynamics of methylene chloride CH2Cl2

✍ Scribed by J.K. Vij†; F Hufnagel‡; T Grochulski¶


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
808 KB
Volume
49
Category
Article
ISSN
0167-7322

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The temperature dependence of the rotational diffusion in liquid CH1C12 has been measured in the far infra-red from 10 to 220 cm-' and 177K to 313K (f.p. to b.p. at lbar). The results are interpreted at 177K and 293K with a molecular dynamics simulation using a 5 x 5 atom-atom potential with charge

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The high-resolution gas-phase 269 nm absorption spectrum of benzyl chloride in the O-O region is reported. A long sequence on the high wavenumber side of the O-O band, assigned to the torsional mode, points to an internal rotation barrier larger in the excited state than in the ground state. This ca