The internal dipolar correlation function for substituted ethanes is calculated by analysis of the rate of interconversion of rotational isomeric states. The states are defined by the location of the molecule on a tetrahedral lattice. The result differs from that of Beevers Williams due to differenc
Dielectric relaxation in short chain molecules
โ Scribed by Robert L. Gaither; Worth E. Vaughan
- Book ID
- 103896565
- Publisher
- Elsevier Science
- Year
- 1979
- Weight
- 765 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0378-4487
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โฆ Synopsis
Models for the dielectric relaxation via coupled molecular rotational diffusion and conformational change in the rotational isomeric state model are described for short chain molecules. The models are compared to experimental determinations of the dielectric behavior of appropriate molecules. Some parameters of the models are evaluated using non-dielectric data.
๐ SIMILAR VOLUMES
The dielectric relaxation of Br-(CH2) N\_ 1-Br, with N = 4 and N = 5, of Br-(CH2) N\_ 1-Br with N = 3 and N = 4 and for 1,2-dichloroethane is deduced using the Jernigan method, where the internal conformational changes are governed by the rotational isomeric state model of Flory. It is found that th
## Abstract A conductivity dispersion has been measured at very low frequencies (VLF) on several concentrated DNA solutions. By measuring simultaneously their electric birefringence decay, it is shown that the dielectric relaxation (which is related to the conductivity dispersion) is due to the mol