Dielectric properties of an epoxy resin and its composite II. Solvent effects on dipole relaxation

✍ Scribed by Jonathan D. Reid; Richard P. Buck

• Publisher: John Wiley and Sons
• Year: 1987
• Tongue: English
• Weight: 515 KB
• Volume: 33
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.1987.070330703

✦ Synopsis

Synopsis

Dipole relaxation dielectric loss behavior of a fiberglass-epoxy composite has been studied following submersion in polar and nonpolar organic solvents as well as in acidic and basic aqueous solutions. Certain adsorbed organic solvents, such a s 1,2-dichloroethane, had little influence on the epoxy relaxation behavior. Other solvents, including chloroform, increased the composite relaxation intensity and shifted the temperaturefrequency region over which the relaxation occurred. Both the amount of solvent uptake and the degree of interaction of solvent molecules with epoxy polar functional groups appear to control the amount of relaxation behavior perturbation. Arrhenius activation energies for relaxation were lowered by solvent uptake from the dry composite value of 18 kcal/M to between 6 and 16 kcal/M, depending on the solvent adsorbed.

Submersion in methanol and chloroform sharply increased the direct current conductivity of the composite. Two molar acidic and basic solutions had little influence on composite dipole relaxation behavior other than the well known behavior assoCiated with moisture uptake.