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Dielectric properties of a hydrogen-bonded liquid-crystalline side-chain polymer

✍ Scribed by Kazuo Araki; Takashi Kato; Uday Kumar; Jean M. J. Fréchet

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
272 KB
Volume
16
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

The dielectric properties of a hydrogen‐bonded side‐chain liquid‐crystalline polysiloxane have been examined over wide ranges of frequency and temperature. This polymer has a side‐chain mesogenic moiety consisting of a benzoic acid and a stilbazole. The observed dielectric loss curves contain a component from dipole reorientation of the hydrogen‐bonded mesogenic group. It has been found to be possible that, using electrical and thermal treatments, such a polymer built through hydrogen bonding can align homeotropically.

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