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Die Trennung und Charakterisierung der Stereoisomeren von N,N′-Äthylenbis-[2-(o-hydroxyphenyl)]-glycin

✍ Scribed by W. Trieselt

Book ID
112379967
Publisher
Springer
Year
1963
Tongue
English
Weight
86 KB
Volume
193
Category
Article
ISSN
1618-2650

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Metallindikatoren VII. Die Aciditätskons
Metallindikatoren VII. Die Aciditätskonstanten und der Eisenkomplex des N,N′-Äthylen-bis-(o-hydroxyphenyl-glycins (EHPG))
✍ G. Anderegg; F. L'Eplattenier 📂 Article 📅 1964 🏛 John Wiley and Sons 🌐 German ⚖ 470 KB

trum of the two isomers the enthalpy difference is found to be -1.30 kcal/mole. Isomer I1 is less stable then isomer I. The entropy difference is f5 cal/mole deg. A pentane solution contains at room temperature 43% of I and 57% of 11, at -104°C 84% of I and 16% of 11.