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Die Struktur von [Li(tmeda)2][Zn(2,4,6-i-Pr3C6H2)3]

✍ Scribed by K. Thiele; H. Görls; W. Seidel

Publisher
John Wiley and Sons
Year
1998
Tongue
German
Weight
51 KB
Volume
624
Category
Article
ISSN
0372-7874

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✦ Synopsis

X-Ray Structure of [Li(tmeda) 2 ][Zn(2,4,6-iPr 3 C 6 H 2 ) 3 ] Abstract. A side reaction of zinc halide containing VCl 2 (tmeda) 2 and Li(2,4,6-iPr 3 C 6 H 2 ) formed [Li(tmeda) 2 ][Zn(2,4,6-iPr 3 C 6 H 2 ) 3 ] ´0,5[(tmeda)Li(l-Cl)] 2 . The crystal structure (orthorhombic, Pbca, a = 26,226(2), b = 19,739( 2), c = 27,223(5) A Ê , Z = 8, R = 0,062, wR 2 = 0,154) contains trigonal planar zinc anions with Zn±C distances of 2,039(7) A Ê (average) and a propeller like arrangement of the aryl rings.

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✍ E. A. Tomic 📂 Article 📅 1967 🏛 John Wiley and Sons 🌐 English ⚖ 90 KB 👁 1 views