✦ LIBER ✦
Die Produkte der Thermolyse von N-(1-Pyridinio)-2-nitroaniliden sind keine Triaziridine, sondern 1, 2-Bis[(2′-nitrophenyl)-azoxyl]-benzole
✍ Scribed by Hans Hilpert; Lienhard Hoesch; André S. Dreiding
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- German
- Weight
- 306 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The products of the thermolysis of N‐(1‐pyridinio)‐2‐nitroanilides (1) had previously been interpreted as tris (2‐nitrophenyl)‐triaziridines (3). The present work shows them to be actually 1, 2‐bis[(Z)‐(2′‐nitrophenyl)‐ONN‐azoxy]benzenes (5). The revised structural assignment is based on the chemical and the spectroscopic (especially ^1^H‐NMR.) properties of 5 and on the results of a X‐ray structural analysis.