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Die Photoelektronen-Spektren methyl-substituierter Acetylene

โœ Scribed by Franz Brogli; Edgar Heilbronner; Volker Hornung; Else Kloster-Jensen

Publisher
John Wiley and Sons
Year
1973
Tongue
German
Weight
382 KB
Volume
56
Category
Article
ISSN
0018-019X

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โœฆ Synopsis

Abstract

The PE.โ€spectra of triacetylene 1 (3), methyldiacetylene 2 (2), dimethylacetylene 3 (1) and dimethyldiacetylene 3 (2) have been recorded. The ฯ€โ€ionization potentials of the unsubstituted acetylenes can be parametrized in terms of a LCBOโ€model.

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## Abstract The photocelectron spectra of nortricyclene (=tricyclo[2.2.1.0^2,6^]heptane) and of triasterane (=tetracyclo[3.3.1.0^2,8^.0^4,6^]nonane) have been recorded and a tentative assignment of the bands has been put forward on the basis of MINDO/2 SCF calculations.