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Die enzymatische Dehydrierung der Stearinsäure zu Ölsäure

✍ Scribed by Karl Bernhard; J. Von Bülow-Köster; H. Wagner

Publisher
John Wiley and Sons
Year
1959
Tongue
German
Weight
303 KB
Volume
42
Category
Article
ISSN
0018-019X

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✦ Synopsis

Some new compounds, including 3 ~, 16%-dihydroxy-pregnan-20-one (I) and 3a, 16%-dihydroxy-allopregnan-20-one (III), have been isolated from urine of patients with clinically compensated adrenogenital salt-losing syndrome. Compound I seems to be responsible for the original salt loss. This effect could be demonstrated under certain conditions in male adrenalectomized rats. Compound I11 was also isolated from hog adrenals. The synthesis of these steroids and of a few others, stereoisomeric in positions 3, 5 and 16, and of a 5,6-dehydro analog is described. There is some preliminary evidence for the presence of compound I and I11 in urines of origin other than patients with adrenogenital syndrome.

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