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Dicyclopentadienyltitanium(IV) pyridine-2,6-dicarboxylate complexes. Synthesis and structural characterization as pentacoordinate titanocene derivatives

✍ Scribed by Regina Leik; Laszlo Zsolnai; Gottfried Huttner; Eberhard W. Neuse; Hans H. Brintzinger


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
875 KB
Volume
312
Category
Article
ISSN
0022-328X

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Reaction of tetracarbonyl[2-{(η 6 -phenyl)tricarbonylchro-quinoline, 2b and 2c, with PhLi and subsequently with MeOSO 2 CF 3 affords deep purple crystalline products 4b and mium-κC 2Ј }pyridine-κN]manganese(I), 2a, with phenyllithium quantitatively affords an acylmanganese anion 3a 4c that have been